Butyltriethylammonium tetrachloridoferrate(III)
نویسندگان
چکیده
In the title compound, (C(10)H(24)N)[FeCl(4)], no classical hydrogen bonds are observed. The butyl-triethyl-ammonium cations inter-act with the tetra-hedral [FeCl(4)](-) anion through weak C-H⋯Cl inter-actions, forming a three-dimensional network.
منابع مشابه
Benzyltriethylammonium tetrachloridoferrate(III)
In the title mol-ecular salt, (C(13)H(22)N)[FeCl(4)], three of the chloride ions of the tetra-hedral Fe(III)-containing anion are disordered over two orientations in a 0.656 (11):0.344 (11) ratio. In the crystal, there are no identifiable directional inter-actions between cations and anions except for Coulombic forces.
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The title compound, (C(6)H(7)N(2)O)[FeCl(4)], contains two carbamylpyridinium (picolinamidinium) cations, which are linked into chains by N(+)-H⋯O hydrogen bonds formed between protonated pyridyl N atoms and carbonyl groups. Tetra-chloridoferrate(III) anions lie between these chains, accepting N-H⋯Cl hydrogen bonds from both H atoms of the picolinamidium -NH(2) group.
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The mol-ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (-) salt [Pandey et al. (1999 ▶). J. Organomet. Chem.592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetra-hedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.189...
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In the crystal of the title compound, (C4H12N)[FeCl4]·C12H24O6, the butan-1-aminium cation and the tetra-chloridoferrate(III) anion have m symmetry: in the cation, the non-H atoms are located on the mirror plane and in the anion, the Fe(III) atom and two Cl atoms are located on the mirror plane. The 18-crown-6 mol-ecule also has m symmetry, with two O atoms located on the mirror plane. The buta...
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The asymmetric unit of the title hybrid compound, (C9H8N)[FeCl4]Cl, comprises a tetra-hedral tetra-chlorido-ferrate(III) anion, [FeCl4](-), a Cl(-) anion and two quinolinium cations. There are N-H⋯Cl hydrogen-bonding inter-actions between the protonated N atoms of the quinolinium cations and the chloride anion, which together with π-π stacking between adjacent quinolinium rings [centroid-to-cen...
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